An argument for pin 1 being ground is if you had multiple voltages - you would always need ground, so start with that on 1, and put other voltages as you work upward.
One handy trick is to use a 3 pin connector. Center pin is V, outer pins are ground. That does two things - it can be plugged in either way without reversing the voltage, and you can wire a ground to one outer pin and shield to the other. For compatibility with that, on a 2 pin connector, pin 1 would be still be ground.