The cells actually total 24V over 2 packs of 12V; the first pack has 4 banks (to reach 13.2V) with 3 cells per bank (to reach ~7Ah); the second is just 4 cells in series to reach 24V for a starter motor (through testing, we determined that ~24V were required for reliable startup).
However, the rectifier will only be hooked up across the first pack, as a result, the voltage will range from 8.0V (2.0/cell -- recommended discharge cut-off) to 15.2V (3.8/cell -- maximum recommended charge); is the difference in voltage high enough for the transients to not matter in this case?
I took some time to read more of the BQ2954 datasheet, I'm surprised I didn't read more of it earlier; I realize now that most of what I'm asking is probably detailed at least roughly throughout it. I'll spend a couple days reading through it to try to understand more of the circuit layout before asking anymore questions, although I'm still pretty clueless about the other elements in the circuit such as transistors, transformers, zener/schottky diodes, not to mention the actual design element of why things are where they are, but I suppose this is the best way to start learning.
Thanks for all the help so far,