>Giaime
I would use NTC, as they are cheaper than optocouplers.
Relays are they used because of their low resistance?
Hi! ok, NTCs are much easier. They're just resistors
I would check with the final circuit that you come up with if the on-state resistance of the optos is low enough not to interfere with the temperature measurement. A rule of thumb could be: if the resistance error induced by the opto is equal or less of the initial tolerance of the NTC (or, if it is worse, the accuracy of your ADC), then I would not worry about it.
You can easily calculate the voltage drop across the on-resistance of the opto by accounting the input impedance of your measuring circuit (ADC, buffers, etc...).
I haven't done the math but the usual 50-100ohm opto on a 10k NTC should be fine, if the measuring circuit is >1Meg input impedance.