you assume the ADC isn't used for other things meanwhile though...
Unless by
meanwhile you mean during the battery sample time, you can use the ADC for other things between battery readings. However, when you want to read the battery you would have to select the battery's ADC input pin and then delay at least long enough for a sufficient RC settling period, based on the resistor you chose, before starting the conversion.
I don't understand why you'd wan't to add more source resistance than necessary for protection (500 ohm), seems like it will only make life more complicated?
The current flowing through the series protection resistor will drain the battery until you disconnect it. The higher the resistor, the slower the battery will drain. This may be important in a low current battery powered situation.
If you're only reading the battery occasionally and not using the ADC for anything else, then there probably wouldn't be any additional complication. Otherwise the only complication is adding a small delay.