So, while it looks good on paper, in practice probably not a good idea. I've been trying to come up with a hway of stepping up voltage for inputting into a Cockroft Walton multiplier, but I don't have a 240 or 320v transformer on hand.
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Some old tube equipment uses a full wave rectifier with just two diodes.
This requires a secondary with a centre tap.
The beauty of this, is that, say a "200 volt per side " secondary as needed for a DC rail of around 200v, will be able to deliver 400volts ac across, the whole secondary, with the centre tap not used.
In Australia, I would say, "Look for an old AM Broadcast radio", but, in North America, post WW2,those were mainly Transformerless designs, so that limits the range of things to either,
very old (1930s) radios, Tube "HiFi" amplifiers, communications receivers, test gear, etc.
I wouldn't mess with the 1930s transformers, as these had quite horrendous secondary voltages, like 570 volts, & 770volts, corresponding to "285 volts a side" & "385 volts a side respectively.
It is quite likely that 80 years has taken a toll on the insulation, so they may be "dead" or "not long for this
world".
As for the other stuff, it would be a sin to butcher a nice old HF radio or test instrument----I don't care about the "HiFi"!
Of course, if you could get someone in Oz to find you an early tube type TV power transformer, you would be laughing, as they commonly were 300v or 350v "a side" corresponding to 600 volts & 700 volts across the whole secondary.
As these were designed for a 240v primary, they would deliver you half those voltages at the secondary when used on.120 volts, & the insulation would be overkill for the job.
I had one, but it ended up being dumped---sorry!
Also, freight may cost too much to make it viable.