Desoldering parts from multilayer PCBs can be a bitch, and even having the best soldering station in the world won't help much.
In this video (from 14:30) I am desoldering a capacitor and a PCI express port using a JBC CD-B station, deliberately set at a low temp, around 320C.
I've found that this is one of the fastest and least invasive desoldering techniques (I believe the best is using Chipquick, but that's kinda expensive).