No. To get 34V for the backlight, the diode has to stand that + the inductor ringing when the current through the diode cuts off which can take its anode negative by the same amount, so it can have 70V across it. Add a moderate safety margin and you are up to 100V.
A motherboard Schottky certainly wont have a 100V rating as the max voltage used for any rail is 12V. Ratings may be as low as 20V.