If your scope isn't capable of handling full mains voltage, or if you'd rather not try, a safe technique is to find an isolating step-down transformer to bring mains down to something reasonable, around 12VAC to 24VAC or so. This kind of step-down transformer is available as a plug-pack for devices that want AC input. I've seen them for doorbells, irrigation systems, and landscape lighting, among other places. They're also included as the first stage of many linear power supplies. With no load, the output of the step-down transformer will be proportional to the input voltage. Just connect one probe across the output of the isolating transformer. This is a relatively safe thing to do.
Another technique, assuming you have a two channel scope that is fully capable of handling the mains voltage on its inputs, is to put channel A on one side of the mains, and channel B on the other side of the mains, and set the scope to display A-B (or set it to display A+B and then invert one of the channels). If you can, limit the bandwidth of your scope, because any high frequencies are just noise for this purpose. Before you attempt this, be absolutely sure your scope is capable of handling the full mains voltage, be sure your probes are also rated for mains voltage, and to be extra careful, only touch the setup with one hand at a time. Sit on your other hand.
But I'd probably use an isolating step-down transformer.