An Antex XS iron purchased new should have the handle labelled with the supply voltage. They are available in 12V, 24V, 115V and 230V models. I suppose its remotely possible you bought a 115V model by mistake so *PLEASE* check the label on the handle. If it came with a fitted UK plux its *extremely* unlikely to be anything other than a 230V element.
A 115V element on 240V would be running at around 100W which would mean it would run extremely hot, burn off flux nearly instantly, badly oxidise the solder tinning the bit almost too fast to use, and would soon overheat and damage the black insulating bush that attaches it to the handle, if it didn't go open circuit first. *NOT* good, so if it is 115V you need to replace it (or at least the element). You could put it on a small autotransformer to buck the voltage to 120V or use a light dimmer to turn the power down enough (around 25%) , but either option is likely to be more expensive than simply replacing the element
Used Antex irons may have had the element replaced or may be missing the label. If you are unsure what's fitted, you need to measure the element resistance and calculate the dissipation at the various possible voltages. The element resistance increases when hot so after ruling out impossible voltages, you then need to try it at the lowest possible voltage, measure the current and see if the wattage is correct for the iron type. If its way under-powered, suspect it of being a higher voltage iron and *briefly* try it on the next higher voltage.
I suspect there was simply a light coating of preservative wax or oil to stop the bit plating corroding in storage and that's all that's burnt. I wouldn't recommend using even a fine abrasive to clean the shaft or bit regularly as that will wear away the iron plating on the bit and reduce is life, and also risks weakening the shaft. If you feel the need to clean it often#, I would recommend bronze wool (available from fine woodworking suppliers and good marine chandlers) as that's softer than the iron plating so wont wear it excessively. You can also use a brass turnings panscourer (NOT a stainless silver one).
Keep the bit lightly wetted with solder while its in the rest and only wipe it off immediately before use. Running a fully wiped clean bit at temperature for too long can oxidise its surface and make it very hard to re-tin it enough to be usable. Apply a small dab of solder to the tip (for thermal contact) after wiping it, then as ebastler pointed out, its apply tip to the joint, then feed into the joint from the opposite side to the bit, enough solder for the required fillet (conical, slightly concave) as soon as its hot enough to take it.
For through-hole work, and SMD discretes*, its generally frowned upon to carry the solder to the work on the bit as the flux burns off typically in under a second so worst case you get a so-called 'dry' joint: a claggy blob of oxidised solder on the joint that hasn't fused properly with the surfaces of the component lead or pad. However you do need a *little* bit of fresh solder on the tip to form a thermal bridge so the pad and lead are heated up rapidly. If you have an absolutely clean tip (or worse an oxidised tip), you wont get enough thermal transfer, it will be hard to get the joint up to temperature and if you dwell on it long enough to do so, you'll cook the pad off the board and will damage any heat sensitive components.
# Preventative maintenance: Its advisable to remove the bit at least weekly in production/rework/repair use and monthly in a hobbyist use and clean the shaft to prevent a buildup of corrosion, oxides and carbonised flux fumes etc. jamming the bit on the shaft. Antex bits can almost always be freed by levering the split open, but there's no point in risking damage when its so easy to prevent.
* There are a few SMD soldering techniques like 'drag' soldering that can legitimately carry the solder on the bit, but they all rely on extra flux pre-applied to the board. Even so, minimise the time from loading the bit to making the joint to minimise the oxidisation of the solder