Unit conversion. L is in uH so it has to be divided by a constant of 1uH to get rid of it; then C /is/ in uF so the expression has to be multiplied by 1uF.
H/F == ohm^2, so they could've used 1/ohm^2 just as well.
More particularly, they could've attached a number to that unit, which you will find is related to either the switching impedance (Vsw(pp) / Isw(pk)) or the source or load (Vin/Iin or Vout/Iout), all of which are at least in the same neighborhood. Seemingly, they assume this is around 1; the 5 sounds like a "magic number", such as ripple% (of the inductor current, or output voltage, or their ratio).
Tim