I have the 100 MHz model of that scope, and here are a few tips I hope you will find useful:
If you want to do averaging on that scope, press acquire button, H1 for acquire mode, F3 for average and use the multipurpose know to set how many samples you want to average. The more samples you use, the more time it takes for the values to settle down, so this will keep noise out. Use acquire, H1, F1 to go back to sample mode. If you're looking for quickly changing signals, you can use H1, F2 to go to peak-detect mode. With it, the scope will display the most extreme values it captures on the screen.
Also keep in mind that you can have up to 8 measurements at the same time, although it looks as if only 4 will fit the screen.
Another thing to keep in mind is that your scope does all measurements and cursor calculations on the displayed data and not on the captured data. So what does that in practice mean? Well it means that if you can't see it nice, it can't be measured nice. For example period measurements and rise times will provide incorrect results at too low sec/div values, voltages will be incorrect if volts/div is set too high and so on. Try to have the actual wave fill as much of the screen as possible.
To get rid of that "1: None is saved" screen at the scope, press the save button, then H3 button to go to Object and show and finally F2 button to set Show to off.
About precision:
Keep in mind that the scope has 3 measurement ranges which it can use. At 10X settings their borders are at 2 V and 20 V. Try to measure your signal with the lowest range that will fit on screen.
There's one more thing that you can do to increase the accuracy and that's self-calibration. Turn on the scope and keep it running for at least 30 minutes, so that it warms up. Then disconnect the probes and press utility button and then H1. Use the multipurpose knob to go to adjust function then press H2, pause for a second (a text screen should pop out now) and then press it again. You should get a screen with a progress bar. Wait for it to finish. Also keep in mind that you need to do this whenever the room temperature changes significantly, since measurements are affected by temperature. If you haven't done this in a while, make sure you do it before you continue to use scope voltage measurements.
My scope's Vk (cycrms in the measurement menu) usually very close to the reading I get from multimeter for DC and low frequency signals.