Probe the surface (standard meter probes, make sure they're pointy enough to make contact, in case the surface is passivated or whatever). Check resistance (first to see if you are making contact, but also to get some idea of the doping -- by my understanding, light P doping is pretty common, but YMMV). Then measure voltage while holding a hot soldering iron (or other heat source) near one probe. The voltage will go positive or negative on the order of 10s of mV. Which sign the heated side exhibits determines the doping polarity. I forget which... JFGI.
Tim