Yeah, normal magnet wire enamel melts and solders at the temperatures where polyimide just begins to sweat. To use it to its fullest advantage, you must use high temperature (usually, polyimide as well!) enamel, and bobbin, and either keep the core a whole lot cooler (ferrites run out of steam much above 100C!), or use a higher temperature material (NiZn ferrite or powdered iron)!
Tim