I certainly can't speak to your experience, but when I became NASA certified, there was never any documentation that specified the temperature to solder at. The was predicated on the work you were doing, the material you were working on and the soldering iron tip you used, but in general we found that 650F to be the best temp. So far as I know the techs I still work with use that temp and across the street where they do mainly NASA soldering that is also the temp they use, +/- a bit depending on what you are doing.
As far as the Metcal tips, my understanding is that two of their series have very high maximum temps (905F and 880F) whereas the rest range from the upper 500's to the upper 700's, that is as a maximum. You don't want run your tips at maximum all the time if at all possible. What they call their standard application tips, the Series 700, are listed as 775F for a maximum temp. Also, considering when working that you aren't always using your iron. You might have a few minutes where you are using it then you put it down to prepare more components for soldering. During the wait time you really shouldn't leave your tips running at 750. But that is just in my experience and those around me, YMMV.