Thanks but, Page 20 was all about Functional description.
Please make sure you're reading the current datasheet, then:
https://www.silabs.com/documents/public/data-sheets/CP2102-9.pdfGoing through the datasheet with a cup of coffee, came out with the one attached.
We're getting somewhere.
Now the self-help is out of the way:
Your Vbus divider will exceed input specs at 5.5V in. Probably not a big concern, but I'd go for 22k over 33k.
The 4.7? cap on +5V isn't really needed, but per-datasheet a 1? ceramic should be there. Realistically, you're fine with 100n on both Regin and Vdd.
Your LEDs are never going to light. You may want to look at other chips in the Silabs range (CP2102N, CP2104) which have programmable I/O, including dedicated LED drive functions.
Showstopper: You're never going to come out of reset.
Oh, and where'd the third ground pin come from?