You can't really do it with this chip; the main switch is built-in, as is the current sense resistor. Trying to put an external switch on it, while "possible", is not going to work well at all - the current mode control loop will not function properly, and this will then break the built-in control loop compensation, likely leading to oscillation.
By the time you finish mucking about with this and deciding it's not going to work acceptably well, you could have paid for and learned to use a modern SMPS controller with built-in gate drivers.
Another option that you may want to consider - if your requirements are not too tight but your budget is - is to use a hysteretic controller such as the MC34063, which can be set up with an external switch, and get away with it due to the control loop technology in use.