If we talk about the main power contacts, then an AC rated contactor can for any given size / type generally be rated to break a much higher current.
This is because the voltage across the open contacts goes to zero during the AC cycle, which means any arcing generated as the contacts are separated when carrying a high current is extinguished in a short time.
As the voltage across the opened DC contactor remains above zero, the arc that is generated upon opening does not stop (without other deliberately designed in "arc breaking" functionality, such as magnetic,compressed air, internal damping compounds or even explosive arc extinguishing) and hence current can continue to flow and physical damage can be caused to the contacts