LTspise is incredibly powerful. UI sucks but some of the most powerful features you can trigger using just the SPICE language. Both Multisim and LTspice are SPICE based and have a similar backbone. LTspice is free, Multisim is expensive. As for Pspice, the light version is free for anyone I think, you could say you are a student or whatever and just fill out the form to get the light version for free but I prefer to use LTspice as it is free without any limitations. A great book for LTspice and the SPICE language is "The LTSpice IV Simulator Manual, Methods and Applications" by Gilles Brocard. Also Pspice seems to be much more laggy and have more overhead when running, LTspice, although the UI is half baked, it runs very smooth and when you know the keyboard shortcuts and spice commands you can become incredibly fast and efficient with the software.