Many moons ago, I did a High Reliability Hand Soldering course run by Telecom Australia.
It was a great course,the two blokes that ran it travelled all over Australia with a couple of big road cases of Royel & Pace rework stations,so you learnt on properly maintained equipment.
Three things in particular were stressed:-
(1) Cleanliness--you had to make sure the joint was clean,plus clean any contamination from the solder before use using solvent on
a Kimwipes or similar,sheet.
(2) Cut the solder before each joint,exposing fresh flux .
(3) Use Liquid resin flux where appropriate
The desoldering tools came with multiple tips,& we were taught to select the correct tip to fit the lead size,reduce the temp to a little below normal soldering temp,place the tip over the lead,so the lead end went into the tip hole.
As soon as the solder began to melt,wiggle the tool to break the mechanical connection,& only then,operate the vacuum pump.
I liked the Royel stuff better than PACE,but it was more expensive,& now has gone out of business.
VK6ZGO