buildingscience.com is a useful resource.
The "building envelope" is the official border between indoors and outdoors.
In my own experience its good if you can agree ahead of time on the building envelope's location and then stick to it. Health problems most often emerge when that border isn't clearly defined..
Here you are potentially adding some additional space to the "indoor" part of the building, or are you?
Make sure you get that straight. How will it be heated? Cooled? You're likely to need more insulation if you get direct sun or get particularly cold weather too. Also, what about drying of walls. Concrete and brick are both somewhat porous, that means if they get wet they need to dry out, how will they dry out?
In the old days most buildings were very drafty and they had so many holes air could just blow in and out through them, but now thats too expensive so buildings are getting better and better sealed. That can potentially cause problems with moisture and condensation.
Carefully consider what happens if you add anything that acts like a vapor barrier. Also, dont put carpeting on a concrete floor without insulation. Where will there be condensation, and where will it go? Also when water falls off the roof, where will it go, good if it can be channeled a bit of a distance away.
What happens if it rains. What happens if it rains a lot. What happens if branches fall. What happens if its really cold or really hot.