... tempco and long term stability wont be stellar, either. I am sceptic about this approach, and for cal you need a 8 1/2 digit multimeter anyway. I think you should try it this way:
- a very good voltage reference (LM399)
- a precision resistive divider made from 0.01% resistors and a *small* trim range
- a high precision Op Amp with extremely low offset, drift and tempco.
- a MOSFET in the driver so there is no base current
- proper compensation to avoid oscillations
- a 100ppm sensing resistor to measure the current
- all this with a very well filtered power supply (batteries are best)
- in a shielded box, if you can with constant temperature.
This could work out with 100ppm, if everything is done properly. Hacking metrology is pointless, because there are so many pitfalls to drop in.