this is not something I need when picking features (deciding what pin to use for what function) and programming it later on.
The table you reference seems to be describing the internal operation of the chip.
As a user, you probably would look at the "Alternate Functions of Port A" table instead; you need to know that if you use a certain function, that will make other functions unavailable (and the exact electrical implicates are less important. Usually.)
In general on AVR chips, you don't get to 'decide' "what pin to use for what function"; at least for hardware functions (uart, SPI, I2C, PWM, etc.)
So you get to notice things like "if I want to use all 8 PWM outputs, I only have one 8bit GPIO port left..."