You could generate two voltages within range of your ADC input. Measure the voltage with your DMM, then with the ADC, and record the results from both. From these point you can find a linear equation that gives you offset and gain (or zero point and full scale point). As Kalvin says, the voltages do not have to be accurate (it could be 1.232 V and 4.129 V for all you care), as long as they are stable for the few minutes it takes to measure them with a DMM and ADC. Batteries could work for this. One AA/AAA battery for 1.something V, and three in series, or a CR2032 3V lithium battery, for approximately 3 V.