I'm also interested in this uC, so I have the User manual handy... let's see what I find:
From page 285/286:
It doesn't really seem to support 3:3:2 per-se, but you could use a palletized 5:6:5 scheme, that will give you 256 colors. But If you want to only use 8 color lines, maybe you will have to use palletized mode and just not bind the low bits of R, G and B.
The Table in page 288 describe which pins are needed for sync, clock, colors and so on.
The table in page 89 shows the mapping from Ports to LCD_xx.
In page 296 the table describes how the palette works and how it is stored, in page 306 the registers are described.
What do you think ?