You say you haven't really connected anything up apart from the few capacitors and pull up resistors, a PIC will run with a 10k or so pull up to VCC, decoupling caps near the power in and a 3.3 / 5V power source depending on the variant.
In that case the 50R resistors should not be fitted, thus not causing issue, I wouldn't connect those 50R resistors by the way, I would use more 270 - 330 depending on the Vf of the LED.
Things tend to heat up when shorted, even if the PIC was in permanent reset it should still stay cool to the touch, if you have no external oscillator and no code running it won't even be really doing anything apart from running it's internal regulators etc, certainly not enough to start heating up.
You may have to post your board files.
Did you mention you were powering from a pick kit or programmer? Try programming the device then powering it from a different bench PSU or something to see what current is drawn, put the current limit on low!! You will soon know if it goes short circuit, the current limiter will kick in.
Even the low spec regulators when shorted can draw 100mA, if it is higher it can theoretically draw more, a USB port is capable of drawing over 1 Amp (out of spec but it can still draw over this!), and that will do unknown damage to your chips.