As far as I am aware, no one is using digital, LMS adaptive-filter-based noise cancelation in a headphone form factor. If anyone has definitive evidence to the contrary I would be *very* interested to see it. The reason is fairly obvious, as already pointed out in this thread: the acoustic delay from a microphone mounted *on* the headphones, to the inside of your ear, is nowhere near long enough to do DSP, unless you gin up something really crazy with analog-based discrete-time processing. The A/D and D/A delays alone would kill you. Now, of course this doesn't matter if the noise is periodic, but in practice those systems don't perform very well, in fact not as well as the analog-based feedback/feedforward combos. (Austria Microsystems, or whatever they are called now, have a whole range of chips intended for this application, and some nice app notes to learn more about it.)
I believe the better analog ANC systems, like the ones from Bose, have a certain amount of digital tunability to optimize performance across different users and varying fit. That's more than enough for a marketing department to claim "digital ANC!!!!"