As far as I see the data, you won't get more power for timeframe of about 100 ms if you raise the voltage much above 30 volts. The higher the voltage, the higher the peak power, but heat dissipation also increses. So the time over which such a high power is available will get shorter. So I would stay in the 28-35 V range, thus something like 22-27 V AC. Peak power of the time of a few 100 ms will go down if the voltage is higher - especially if the heat sink is not exceptionally large.
If you really need more power consider one more amp/ speaker or a discrete transistor amplifier instead of a chip.
You may not need such a large transformer, as normal speaker can't stand high power for an extended time too. A 100 W speaker may have trouble dissipating more than constantly 20 W for am hour. It's better to have the amplifier to signal a power limit because of a hot transformer that to burn the speaks.