Dual slope on the edge that you noticed.. Out of curiosity, i would like to understand why is there.
I like the MOSFET drain-source saturation explanation.
As I said, to try one chip inexpensive solution, I already ordered few 74LVC14 single gates... They are fast, SOT23, minimal parasitics...
LVC/ALVC was one of the candidates I considered. I do not remember what 5 volt logic I considered. I looked specifically for tristate outputs which can be configured to operate as N or P channel open drain outputs like the 74LVC125.
I agree with you, clean, well defined edge, is more important than speed...
For checking compensation and vertical calibration, a surprisingly slow edge speed and low fidelity can be tolerated so that part of the design is trivial. Some precision pulse generators with linear (class AB) outputs are more than fast enough.
High fidelity fast edges are a whole different matter requiring careful layout and special parts. The fast edge outputs on the PG506 have the termination resistors built into the BNC connectors.
I like your proposal for bipolar cascode and fast small signal schottky diode cutoff into single 50 terminator right on the BNC.
I'm studying schematics you showed....
The problem is that it will require more than a 3 volts. It might just be possible on 5 volts but higher would be better.
Below are a photographs of the construction of the PG506 fast outputs to show what can work and the full schematic. Tektronix managed it with air wired through hole parts so I think a surface mount implementation can do better. Those little resistors are 1/8 watt carbon composition which have low parasitics except of course for their lead length. Some of the complexity is to make up for the non-ideal construction.
Things to take special note of are how the BNC connector attaches to the printed circuit board almost forming a coplanar waveguide and the high performance 50 ohm termination which is built into the end of the BNC connector in the form of a disk. A simple design will use a 50 ohm transmission line to the BNC and a 50 ohm termination probably made from a pair of 100 ohm resistors.