What kind of quantity are we talking here? I don't see the point in winding your own coils unless it is a one-off. Judging from your replies about the cost of 'rig to wind coils' I'm thinking you need >20 units.
Using offset hall sensors on the mains cable along with a couple of comparators could work, with parts well below $5 US, but then you have to get the PCB's made up.
You mention about the negative voltage from a rogowski coil. Why does you need to measure the negative voltage at all? Or even why use an ADC? I thought you were after just knowing when the appliance is on or off, in which case no need for a precision rectifier, just resistors, diode clamps, and a comparator would do. If you're worried about negative voltage, a simple schottky from ground to signal should prevent the MCU's input clamp diodes from being forward biased.