The vendor says that it's aluminium alloy, not pure aluminium. Aluminium alloys with silicon and/or magnesium can look a darker grey, apparently. Or maybe it is even anodized?
I don't think it is painted; the color looks too even on the inside. Low-cost spray painting is typically just applied to the outside, with some "fog" visible inside. And since they claim to have two cooling fingers to touch the main chips on the Raspberry, painting it from the inside would actually be detrimental.