Deciding the crossectional area for a high current cable isn't always easy.
It depends on many factors: current, maximum acceptable voltage drop, conductor material, ambient temperature, maximum temperature rating of electrical insulation and surrounding materials, the number of neighbouring conductors in the conduit/sheath and the thermal insulation of the surrounding material.
For a start answer the following questions:
How much current are you drawing? Give the typical DC/RMS figure, not the surge.
What's the maximum acceptable voltage drop?
Are the cables well ventilated?
Low voltage high current cables are, in many ways more dangerous than high voltage low current cables because the amount of heat given off can easily start a fire. It's very easy to get it wrong, for example you buy a 25m length of PVC insulated 1.25mm² mains cable which is rated to 13A. You put a plug on one end and a socket on the other end to make your own extension lead. It's too long for some applications so you coil it, you then use it to power a heater rated at 13A and after a couple of hours of being left on the cable melts and catches fire. The cable should have been derated when coiled because the heat couldn't escape causing it to become dangerous. You should have used a heavier duty cable with a higher temperature rating and larger crossectional area if you wanted to coil it and power a 13A heater.
A good section of the IEE wiring regulations is devoted to choosing the right type of cable for the job: you should look at the regulations relevant to your jurisdiction.