Combining PV with a solar boiler could be a good idea.
Thermal solar is better than PV+heat pump boiler, from the efficiency side.
A combination of both is a good system IMHO.
The efficiency difference of max 20% is however not relevant when speaking about solar, as you increase the area to compensate, and you overdesign anyway.
A PV+heat pump boiler has advantages over thermal solar+PV that you can use the excess energy in the summer as electricity instead of wasting it, and the installation cost is lower with one less medium to route to the roof.
As usual, YMMV depending on eventual subsidies, local weather pattern and local prices.
Storage of thermal energy in the thermal inertia of a concrete floor works but is limited.
Say you have a 10-ton concrete floor, which can increase temperature only + 5°C. Don't burn your feet !
You store less energy in that 10-ton concrete floor than a 1 m³ water storage which can increase temperature 65°C (30 to 95°C)
Also, one giant drawback is that you don't control the release rate of that thermal storage.
Thermal inertia works, and is a fact in most buildings, but it will not really help that much on the long run, especially if you want a tightly controlled temperature.
Also, of course, the concrete floor needs to be well isolated to the sides of the building and to the ground under.
Those are requirements anyway for properly energy efficient modern buildings.
For the record, I have a near passive house, wood structure and concrete floors, with 10m² thermal solar + 1,3m³ water tank + a wood burner (very efficient and clean). No PV yet.