Peltiers might be what you're after, I don't think they're that efficient though, but still a neat idea. I always thought it would be neat to setup a wood stove and power any electronic/electricals (fans etc) with a bunch of peltiers. That way the entire setup is self contained but can still be high tech. Ex: have water pumps, solonoid valves, etc... Basically it would just charge a battery and everything runs off the battery.
Another tech is the sterling engine. I don't know why this is not used more, I think it's based on the same concept as steam except it's a gas so it does not need as much pressure to work. I recall seeing this cool setup where it was basically solar collector dishes that power a sterling engine. They were maybe like twice the same size as one of those old style TV dishes and tracked the sun and generated several KW. These things come out, generated real power and shown on TV, then we never heard of them again. Not to be into conspiracies... but it does make me wonder if these new inventors get given tons of money to shut up or something.