Do the 0C/100C verification, though you will find it is up to 5C out at the high end, and assumes a 25C ambient temperature ( short out the terminals and you will generally see it read around 25C, irrespective of ambient actual), so it will be accurate to within 20C at 200C in most cases. Good enough for just seeing if you are within a ballpark, though if you have some proper 63/37 solder you can see if the melting point of it is roughly 183C where it gets pasty, 60/40 solder is close enough to eutectic to use, just has a slightly larger plastic range. Lead free solder you need to know the actual solder melting point, which is quite well controlled for name brands.