copper coated alu is pretty common in chinese stuff, alu is the next best thing to copper; it is about 60% as good of a conductor, buy is significantly lighter, cheaper and more corrosion resistant. with copper coated alu you don't really have to worry about galvanic corrosion along the length of the conductor as the copper covers the outside, only at the terminations are they both apparent.
I am a pretty proficient TIG welder, i'm able to do autobody no issues and have "shown off" my skills many a time welding soda cans together. That said, I would never TIG weld anything electronics related. Aside from the process being pretty dangerous for electronics components, you have relatively little control and accuracy compared to an iron. It just doesn't seem right. That said, previously I have tig welded lithium pouch cell terminals because a spot welder was unavailable, I was hesitant at first but as the material is so thin is it VERY quick and you don't heat the cell much at all.