As said in the video, the tip of the antenna is high voltage, high voltage high frequency applied to PVC is going to make it heat up a lot, as it is quite lossy compared to better plastics. (The PE-4 sheet mentioned in the video is UHMWPE, much less lossy)
As mentioned above, skin depth plays into it too. About 17um deep at 14MHz, on 2.053mm diameter 12awg wire leaves 0.11mm^2 in use. A 5m long antenna would have 1.7 ohms of resistance then. I^2 R losses in a resonant antenna become very not fun then.
Heat from the copper surface, heat in the plastic. Even if there wasn't a dielectric breakdown of the air at the tip to light everything off, it could have started to char the PVC (conductive, but very resistive) and had everything go to crap from there.
Unexpected? Probably not. Could I tell you at what power level the antenna would go up in flames? Probably not