Doherty is 1930's technology, heavily used by high powered medium wave transmitters running up to 600 KW.
At unmodulated carrier the Class B stage (Carrier) is saturated, whilst the Class C stage (Peaking) is turned off. At Peak Envelope power, both stages should be saturated and therefore giving maximum efficiency. From memory the power efficiency of the amplifier looks like a bathtub curve were maximum efficiency is at 0% modulation or 100% modulation, and least efficient at 50% modulation.