I figured it out. Long story made short, I overloaded some cells in MS Excel. The maximum number of characters in a cell is ~32k and I was trying to stuff a few more than that into a single cell.
Background:
The issue stemmed from my college and I using two different libraries for resistors. I was using a Panasonic lib and he was using a Rohm. When we combined the design and ran the BOM generation tools, the system would die (see above). Well, it turns out that Altium combined the like 0603 resistors into single rows (which is what we wanted) (also note this is a really large board with a lot of analog comparators, opamps, NPNs). However, Altium then comma listed a separate part number for each, for example 10k used like this: P10.0KHCT-ND, RHM10.0KHCT-ND, RHM10.0KHCT-ND, RHM10.0KHCT-ND, etc. The cell overflowed, Excel choked, and some error is not well handled.
K.