Making a 24V UPS is not hard, all you really need is a 27.6V PSU and two 12V VRLA blocks.
If you want to put loads on the midpoint, you need to use two 13.8V PSUs, and you need to size the batteries proportionally.
Problem is that most VRLA batteries dont live long that way, the six cells in the 12V battery are slightly different, so some will be overcharged and some will be undercharged with the net result that the battery probably only last 3-5 years before one of the cells either fails open (harmless) or closed (hot!).
The next step up is to do "equalization charge", that's the "three step charging" you will read about, but if your power is generally good that will not be enough.
Equalization charges should be performed every 2-4 weeks, and none of those "three step chargers" do that. (Hack: put a timer on the mains, which interrupt 5 minutes every three weeks, to kick the charger out of float.)
The next step up is to use 2V cells, where you charge each one individually (either with separate chargers or with load-balancers).
There is a huge gap in available capacity between the 6Ah cylindrical and 100Ah OPzS/OPzV cells, but if you go with OPzS and refill water every other year, your batteries will last 25 years.
So the very first thing you need to do is calculate the capacity you need, and decide how often you want to buy new batteries.
I have tried the 12/24 thing myself, but it was not worth the complexity and I had trouble with cable/connector losses. I²R rules: You need much more copper in 12V cables than 24V cables.
I have switched to pure 24V UPS and feed the 12V stuff with distributed DC/DC converters (Traco TMDC).
And whatever you do: The first thing you bolt to the battery is an ATO-fuse (For instance with something like this:
https://powerwerx.com/atc-ato-inline-fuse-holder-18-gauge-red) because even small VRLA cells will deliver hundreds of amps when shorted.
Also: Siemens makes some damn good "Simatic" 24VDC UPS kit, and you can often find it cheapish on eBay.