For Through Holes, I'm usually using a soldering gun instead of a soldering iron. The soldering gun tip does not have a big thermal inertia, and it is powered only when the trigger is pressed. The advantage is that you can easily control the tip temperature of a soldering gun by how long you press the trigger.
To apply solid rosin, heat the tip of the soldering gun just a little, enough to melt the rosin just a little, until the consistence of honey. Deep the tip into the rosin for 2-3 mm, then release the trigger and remove the tip from the rosin. As a result, a few mm cubes of rosin will solidify on the tip of the soldering gun, without burning the rosin. The tip loaded with solidified rosin can now be heated again on the soldering junction, simultaneously heating the PCB trace, the component terminal, and the soldering alloy.
Solid rosin does not work too well with a normal soldering iron, because the rosin is burned/vaporized too fast at normal soldering temperatures.
One more thing: In my experience, solid rosin is good only with SnPb solder.
For lead free, nothing can beat dedicated lead free flux, because the lead free flux can outstand the higher soldering temperatures required by Pb free alloys.