Hello new299,
according to the paper you linked about the AD5791 DAC, it should have an integral linearity of < 1ppm.
Noise vs. speed is another important parameter, which is not specified there, but may well influence your scanning microscope..
Several kHz of stepping is common for these, as far as I remember.
So, settling time comes on top.
High sampling rates usually reduce the effective resolution, that also goes for your DAC.
To characterize these 3 parameters, you'll need something better, i.e. linearity << 1ppm, 1ms A/D speed with high enough resolution, low noise.
6 1/2 digit DMMs from HP / Keysight are at par - at most - with your DAC.
Other 24bit ADC suffer either from non -linearity, or from noise or both, and therefore are not suitable.
The 3458A therefore is the best choice for your needs. It's got 0.02ppm linearity, < 0.1ppm / < 1uV /10V noise and resolves 6 1/2 digits down to 100usec aperture.
You may check TiNs thread about noise measurements on common DMMs, to search for a cheaper alternatives from Keithley or other manufacturers, if only noise has to be characterized.
Frank