It is an amusing choice, since "6.2" is the closest E24 value
You're on the right track -- off just a little on the multiple!
The
Renard series has 1, 1.6, 2.5, 4 and 6.3, and splitting 40 into 35 (nearly an R20, bleh!) and 50 (an R10) is convenient for practical purposes. 80 (an R10) is also often seen.
This breaks a bit at higher voltages, where 160, 200, 220 (uncommon), 250, 350, 400, 450, 475 and 500 (and sometimes 550, 600 and 630) are seen, I think again for practical reasons, as these are approaching the physical limitations of electrolytic capacitors (or surpassing them; as far as I know, "630V" electrolytics are actually internally series connected).
Film capacitors pick up again from 400, 630 and 1000V, but oddball values are also commonly seen here, probably driven instead by standards -- ratings related to RMS, nominal-maximum, peak, etc.
Tim