Qualcomm, NXP, Broadcomm, Infinion, Synaptics, Murata, and Marvell are all common in commercial products. The issue is their documentation is mostly confidential, so hobbyists won't be able to use them (easily). In many cases, there will be large minimum order quantities.
The chipsets often will use QSPI for 802.11, plus a UART for BLE. Often the MCU is separate from the radio chip. For example, the Cypress CYW43439 has both WiFi and BT.
It sounds like the target is a hobby products? (I'm surmising from the request for easy to solder parts). You might want to stick with the ESP32 (due to parts availability) and use an external ADC or even external MCU to cover the weaknesses of the ESP32.
For small production runs, a company would likely choose a pre-made module (due to simpler compliance testing). For mass production, you'd use the bare IC and integrate the RF matching components on your custom PCB.
In terms of learning, I don't see any issue with using the ESP32. In terms of easy of manufacturing, definitely buy a module. The u-blox NINA-W151-03B looks interesting and is in stock. (EDIT: Oh, Kean noticed that these are actually ESP32... ) Laird and Espressif modules also have stock... you might be able to find something from Silicon Labs, too.