The MCP1640 is a great little chip, but its quoted efficiencies are overly optimistic (like all datasheets!). Note there are 4 versions, with combinations of PWM/PFM and output disconnect on shutdown, and output bypass (pass through).
I don't think you'll get 100mA 3.3V output of it from a single alkaline or NiCD/NiMH. I haven't managed to get that from the SOT23-6 version, but the DFN version surprisingly did better, despite no indiation in the datasheet of differences.
From memory, the lowest startup voltage I tested it with was 0.95V, driving a single white LED @ 3.2V output. I never did fully test one over the whole Vin range though.
There are many single cell boost converters, but not all are synchronous and as such, can't disconnect the output from the input during shutdown - it's much mroe common these days, but not a guaranteed feature.