I think you have mostly picked the wrong questions. From an electrical point of view, all mats from reputable manufacturers/suppliers, when used correctly, will protect against ESD damage as intended.
What will make a huge difference are the mechanical properties. Temperature resistance as already pointed out, but also scratch/cut resistance, abrasion resistance, chemical resistance (liquid flux, circuit board cleaner, other solvents), softness/hardness of the work surface, grip/slide resistance, etc.
It is the non-electrical properties where you get to make your choices.