If its only ever going to be 100 deg, then great, just measure the resistance of the thermistor at 100 deg and use that in a simple voltage divider to the ADC of your pic. But if you are going to be measuring the Temp,or be using the temp for anything else, your going to have to do a lot more work. Thermistors are not linear, and you will have to use the
Steinhart Hart equation in the pic to get the correct temp from the curve. Looking at the Steinhart Hart it looks complicated, but when you come to use it, its not that bad. You just need 3 points on the curve as reference. These are mostly given on the data sheet, but you can measure the three points. You then pump these into the equation along with your reading from the ADC and you get your temp. The problem doing it this way is that you will need floating point math in the pic, this is slow and can take a lot of space. Another way would be to pre-calculate a table and use that in the pic, then no math is needed, except for maybe interpolation. There are many examples on the net and many different ways of calculating the curve, Google is your friend here.