Teflon is PTFE, Poly-Tetra-Flouro-Ethane
poly-(tetrafluoroethylene). The monomer is required to be unsaturated in order to form the bonds that make the polymer. And flour is not involved.
Typos don't invalidate the point.
Biocompatibility needs to be understood in the context of material handling and how it gets used. For example, PTFE treated non-stick cookware should not be heated above 500 °F or toxic byproducts can be released. That temperature isn't hard to reach at all on a gas range. For small molecules, inertness isn't an unalloyed blessing: being biochemically inert (no breakdown pathway) is a prerequisite for bioaccumulation. Carbon nanotubes are both inert and carcinogenic.
The original context was food grade lubricants that contains PTFE, not non-stick pans, or the breakdown products at high temperature. The original quote was "Teflon is an endocrine disruptor", baldly, no qualifiers, no mention of breakdown products at high temperature. As for biocompatibility, PTFE is highly biocompatible at normal temperatures, it gets used in medical implants precisely because of that, it's even used as a coating on implants to passivate things that are less biocompatible. Uses include: repairing vocal cord defects, arterial grafts, orthopaedic joint implants, reconstructive facial plastic surgery, stents and replacement heart valves. The toxicity of other things, small molecules or not, is not in question.
Cdev has a habit of promulgating left field, scientifically unsupported, conspiracy theory style misinformation. i.e. The implicit idea here that PTFE is dangerous to you, when it is not. He appears to be a nice, well intentioned guy, but he just keeps on posting this irrational stuff. If you go and support the idea, by extrapolating from normal conditions to construct some set of conditions where it could be dangerous you're just encouraging the spread of disinformation. Heck, if you're really unlucky he might regard you as a fellow traveller and start privately sharing his insights into economic theory with you - that should be discouragement enough alone.