You raise some very good points re: disposal of contaminated etchant, but in the quantities needed to wet a Q-tip or a couple of ml in a bottle cap, as I used to dip the above grabber top, it isn't an issue for hobby use - wipe the few drops remaining up with kitchen paper, bag it and trash it. OTOH if you are at any sort of business that produces hazardous waste, *ALL* hazardous waste must be disposed of properly and most importantly LEGALLY. Also I forgot to emphasize that you need to avoid contaminating your 'stock' bottle of whichever copper salt solution - I thought that would be obvious to anyone who remembers their college chem, but maybe I'm too optimistic?
On the contaminated copper etchant disposal side of things, as a hobby user, why are you trying to recover copper metal using aluminum? Unless you have a use for very fine copper powder, surely it would make more sense to precipitate it out as basic copper carbonate using sodium bicarbonate or as copper hydroxide using lime, then mix the sediment with cement and powdered limestone and cast it in disposable containers to lock up the copper salts as a solid lump in an alkaline environment that will keep them insoluble.