The terms "VA" and "Power" are very similar ... sort of. VA is used to describe the capability of a power source. Watts is a measure of the power used by the load. Both are calculated using Voltage and Current, with a little extra something....
Let's start with the simple case:
If you have a purely resistive load then a 100VA rated transformer can deliver 100W into that load - assuming the resistance is such that the maths works out. For example, if the secondary voltage is 20VRMS and the current capability is 5A (again, RMS) then the resistor would need to be 4 ohms. If the secondary voltage is 100VRMS and the current capability is 1A (again, RMS) then the resistor would need to be 100 ohms.
In the case of the first example (20V/5A) the transformer is capable of deliver 20V at up to 5A - but the caution here is to pay attention to the phase angle between the voltage and the current drawn by the load. For a purely resistive load, the phase angle is zero and the maths is easy (as shown above), but when you have an inductive or capacitive load, there is a real difference in that phase angle.
The end result is that for reactive loads, you may indeed have a transformer that is supplying 20V (as you measure it with a multimeter) at 5A (as you measure it with a multimeter), but the load may only be dissipating 80W - because of the phase angle between voltage and current is not zero.
This apparent discrepancy is called "Power factor".
The power factor for the resistive load examples above is 1, while the power factor for the reactive load is 0.8.
Aiming to keep the power factor as close to 1 as possible is a key objective in several situations - which is why you may have come across mentions of Power Factor Correction (PFC).