All analog systems are non-linear: the correct question is how to quantify the non-linearity. Non-linearity will depend on signal level. Possible answers, depending on what type of system and available equipment:
1. For an amplifier, if you have two variable attenuators of known accuracy. Connect generator through first attenuator to amplifier input, and connect appropriate meter through second attenuator to output. Start with second attenuator at reasonably high attenuation and adjust generator and input attenuator to achieve “reasonable” level at meter. Proceed to increase input attenuator (decreasing amplifier input), noting output attenuation required to obtain same meter reading. This old-fashioned method does not rely on wide dynamic range accuracy of generator level or meter accuracy.
2. Use an distortion meter (or spectrum analyzer) to measure distortion products as a function of signal level. Either harmonic distortion or two-tone modulation products.
Linearity is not exactly synonymous with proportionality, when there is a constant offset with zero input for DC systems.
What kind of systems are of interest to you?